It may never be known with certainty who invented the first explosive, black powder, which is a mixture of saltpetre (potassium nitrate), sulfur, and charcoal (carbon). The consensus is that it originated in China in the 10th century, but that its use there was almost exclusively in fireworks and signals. It is possible that the Chinese also used black powder in bombs for military purposes, and there is written record that in the mid-13th century they put it in bamboo tubes to propel stone projectiles.

There is, however, some evidence that the Arabs invented black powder. By about 1300, certainly, they had developed the first real gun, a bamboo tube reinforced with iron, which used a charge of black powder to fire an arrow.